Radioactive dating and carbon 14 and nitrogen 14
Research has been ongoing since the 1960s to determine what the proportion of in the atmosphere has been over the past fifty thousand years.
The resulting data, in the form of a calibration curve, is now used to convert a given measurement of radiocarbon in a sample into an estimate of the sample's calendar age.
In addition to permitting more accurate dating within archaeological sites than previous methods, it allows comparison of dates of events across great distances.
Because the time it takes to convert biological materials to fossil fuels is substantially longer than the time it takes for its in the atmosphere, which attained a maximum in about 1965 of almost twice what it had been before the testing began.
Measurement of radiocarbon was originally done by beta-counting devices, which counted the amount of beta radiation emitted by decaying atoms in the sample and not just the few that happen to decay during the measurements; it can therefore be used with much smaller samples (as small as individual plant seeds), and gives results much more quickly.
By contrast, methane created from petroleum showed no radiocarbon activity because of its age.
The results were summarized in a paper in Science in 1947, in which the authors commented that their results implied it would be possible to date materials containing carbon of organic origin.